Crude Oil Contaminants: Chlorine and the Desalting Process
Online Chlorine Analysis in Liquid Hydrocarbon Process Streams
With ever-changing crude quality and blends, chlorine levels can shift quickly, making real-time analytical results invaluable. Clora® Online delivers real-time,continuous analysis of total chlorine from 0.2 ppmw up to 3000 ppmw. By monitoring desalted crude, a plant can optimize performance and immediately see impacts of crude changes (including organic chloride). Powered by MWDXRF®, Clora Online uses ASTM D7536 technology and is ATEX and NEC certified.
Crude oil contains many contaminants which present challenges to refiners. Some contaminants occur naturally in the crude oil and others are accumulated in the upstream process. The primary means to remove these contaminants is the desalting process.
In the desalting process, water is mixed with the crude, passing through a mix valve prior to entering the desalter. The mix valve creates vigorous contact between the water and crude resulting in an environment for contaminants to enter the water phase. Once in the desalter, a current is applied to help accelerate the separation of the oil and water phase. An emulsion breaker may be used to aid in separation. The water with any solids that might have been in the crude is sent to the wastewater treatment plant for treatment.
Any contaminants not removed by the desalter must be treated chemically. The chlorine remaining in the desalted crude is particularly important. Chlorine can exist as either inorganic chlorine (calcium chloride, sodium chloride, and magnesium chloride) or organic chlorine. Typically the inorganic chlorine will be removed in the desalter, but organic chlorine will stay with the crude oil.
Chlorine can cause corrosion in the crude unit by forming hydrochloric acid. Chlorine can react with amine-based treatments to form ammonium chloride, which can deposit in overhead systems. Heat transfer can be impacted and under-deposit corrosion can result. Treating chlorine in crude units is a balancing act. Too much chemical will increase fouling potential and put downstream equipment at risk. Too little chemical presents a risk of corrosion and fouling in the crude unit. Accurate measurement of chlorine is vital in protecting your assets.
Clora Online accurately measures total chlorine in raw crude oil, desalted crude, or both. Real time results give the feedback that is critical in keeping systems running properly. Desalter performance can be monitored to make sure it is working optimally. A proper performing desalter will keep the crude unit and downstream units operating well and protect the waste water treatment plant from overload. Desalter upsets can easily be detected and impacts of crude slate changes can be identified.
Clora Online can also measure total chlorine in water streams giving flexibility based on your needs. Measuring chlorine in the overhead waters or desalter wash waters can be easily completed, even if they are sour. These measurements can be used to automate chemical feed, protecting systems around the clock.
The desalting process is critical to the refinery. Clora Online helps ensure quality and avoid issues through the highly accurate measurement of chlorine in raw crude oil.
ADVANCED ANALYSIS WITH MWDXRF
Monochromatic Wavelength Dispersive X-ray Fluorescence (MWDXRF) utilizes state-of-the-art focusing and monochromating optics to increase excitation intensity and dramatically improve signal-to-background ratio compared to traditional WDXRF instruments. This enables significantly improved detection limits, precision, and a reduced sensitivity to matrix effects. A monochromatic and focused primary beam excites the sample and secondary characteristic fluorescence X-rays are emitted from the sample. A second monochromating optic selects the sulfur characteristic X-rays and directs these X-rays to the detector. MWDXRF is a direct measurement technique and does not require consumable gasses or sample conversion delivering robust and low maintenance analyzers with dramatically lower detection limits and faster response times.